1937年，上海沦陷，出身外交世家的普济州因不满与姚素珍指腹为婚，在其婚礼上，竟然当场逃婚，辗转至中国驻奥地利维也纳领事馆任职，并与其偶像――女小提琴家海伦雨中邂逅。1938年，奥地利被德国吞并，纳粹疯狂迫害犹太人，犹太人只有拿到外国签证，才可以逃离奥地利，但各国忌惮纳粹，以各种借口拒办签证，惟有中国驻维也纳领事馆，向犹太人敞开签证大门。普济州秉承总领事旨意，顶住重重压力，冒着巨大风险，与领事馆同仁一道为犹太难民办理通往中国上海的签证，尤其在独力执行“七人名单”绝密任务中，与以汉斯为代表的德国纳粹斗智斗勇、巧妙周旋，在犹太抵抗组织的配合下，历尽艰险，冲破重重险阻，将一个个大科学家找到并救出，展现了中华民族至情至善的人性光辉。
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普济州与嘉丽、鲁怀山带着唯一一张签证来到罗莎母子的藏身之处，想要劝服罗莎现行离开，孩子由他们保证安全。但罗莎放不下孩子，不愿离开。普济州只好让她用这一张签证去海关处试试，能否同时让着母子俩安全离开。罗莎动摇。
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欧力克为了爱德华先生的科研成果，找到了普济州住处，请求他能将科研成果送出去。普济州遵守外事纪律拒绝了。欧力克替大卫向普济州道歉，解释罗莎是善良的，她所做的一切都是大卫逼她做的。并道出大卫为了弥补良心的谴责，曾帮助普济州送走过史迪尔先生和克庞贝先生的事。嘉丽替济州原谅了他们。济州问得罗莎的藏身处，告诉…
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布朗从罗莎的着装上判断出她是从集中营逃出来的人，罗莎惊恐万分，却得知布朗是犹太人身份。放心下来的她留下遗言，如果自己出事，就把未出世的孩子托付给布朗。此时，汉斯带人找上门来。
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