康熙帝微服上街，偶遇女扮男装之亲王府格格傅怀玉及平西王吴三桂世子吴应熊，因缘际会地做了结拜兄弟，直到日后他们身份揭露后，康熙与吴应熊却同时爱上了怀玉，遂衍生出难以化解的爱情三角，康熙为政治考虑，有意招应熊为额驸，赐婚建宁公主，并有意纳怀玉入宫，立做皇后，此举引发贵人成韵之妒恨，乃在皇太后面前不断献谗，并对怀玉施以无情的打压与陷害……
怀玉多次遭陷害，总被康熙适时解围，康熙为表明对怀玉的真情，不惜与太后反目，然而在此同时，怀玉不可告人的身世只谜却被揭发出来。原来怀玉是南明永历皇帝的女儿，於战乱时被亲王傅正所抱养，当怀玉得知自己的身世及与康熙与生具来的国仇家恨，顿时陷入矛盾的苦痛与深渊，因这时的她已身许康熙，并怀有龙子。
成韵一心想登上后座，在得知怀玉身怀龙种後，更变本加厉的加害怀玉；应雄虽奉旨娶了建宁公主，仍对怀玉恋恋不舍；康熙身为一国之尊，却因怀玉敏感的身世，饱受太后及文武群臣莫大的压力。乃被迫在政治与爱情之间作一选择。怀玉与康熙二人，情路走来磨难不断，备极艰辛。终於藉彼此的真情挚爱，瓦解了重重阻碍，走向完美结局
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